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General Discussion

General discussion for the Flow Battery Research Collective

This category can be followed from the open social web via the handle general-discussion@fbrc.nodebb.com

40 Topics 512 Posts
  • New member introduction thread!

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    kirkK
    Welcome @saphnich and @rowow ! Membranes are definitely something relevant to our work here, to date we have avoided ion-exchange ones like Nafion due to the high cost but having a low-cost and open-source option would be great. I'll hop into the thread @rowow started on DIY membranes. @rowow said in New member introduction thread!: Secondly, using foam core PVC sheets which are readily available and cheap from cabinet shops like imeca allows for complex flow cell designs to be easily and rapidly produced with a simple CNC router on various sizes. I have a flow cell design already I'll be glad to upload. This would be great to see! Feel free to start a thread in @general-discussion about your cell design. We had tossed around the idea of 2D-material milling/laser approaches to flow frames, but have stuck with 3D printed designs for now so that we can have internal geometries in the flow frames - 2D would certainly be easier and cheaper to make, but I was hesitant about the increased gasketing required/adhesives for sealing.
  • You Tuber Video on an open source all Iron battery

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  • Upcoming improvements to the dev kit

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    I just had get the .stl files for the end-plates and I will print them
  • My Suction Luer Lock

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    Thanks for sharing your pictures! It always makes us very happy to see anyone reproducing the kit independently. You can see my current setup below: [image: 1771584465302-cell_feb2026-resized.jpg] I am testing the double reservoir with spill-over communication (that's why the reservoirs look different and are at the center). My pumps are connected in a suction configuration and they enter and exit the cell on their sides. When you have pumps in a push-through configuration having the flow going from bottom to top is important to push air out, but when you suck through the cell the vacuum will push all air out and fill the entire cavity, almost regardless of how you pump. I haven't seen any air being trapped there (no bubbles are evident when shaking or moving the cell so that the flow is in either direction). As you can see I have changed some connections to luer locks, except the connections for the pumps. I however like how you've made them ALL luer locks, much simpler to disassemble. As you can see I'm also testing the new clamp-compatible end-plates and clamp. This works SO much easier than the screws, since the compression is centered I am also experiencing fewer problems with the cell and slightly better energy efficiencies since the felt compression seems to be more uniform. Opening and closing this cell is a breeze compared to the screws. I used PLA with 80% infill to print the end plates but I am sure PETG will work great too. About the PP, it is a bit tricky to find the PP and printer settings that work best for water tight results. I am using the Ivor white PP from smart 3d, which has worked well on the prusa core one. In any case, let me know if there's anything I can help you with.
  • New ion exchange membrane recipe using water softener resin and PVC cement

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    @rowow We don't have the equipment or time to prepare these membranes but if you send us samples of 100-400um thick membranes we can test them out.
  • Using cnc router cut PVC foam boards as cell frame

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  • Designing the large-format cell

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    kirkK
    Did another leak test today with water, correctly with 2x ~12 mm plywood endplates each side. Saw no leaks through the edges which was great news, but the barbed connections on the cell showed signs. Also, the MP-6R pumps struggle with the current flow frame design, which has 0.8 mm wall thickness and a 1 mm internal channel (electrode area therefore 2x0.8 + 1 = 2.6 mm thick). I remade (and pushed to the repo) the flow frame with a 3 mm internal thickness, in order to alleviate this pressure drop. Here is the test setup, I ran out of tubing (ordered 2m but they sent 1 m ), so the connections aren't ideal but this time no kinks in the flow path. Note, I put these drain valves in, of course they are pointing the wrong way for now, will need to elevate the setup so they can point down in the future. [image: 1769764493660-9fafda86-7f70-439f-9ecb-eeb9a7316215-img_20260129_153901-resized.jpg] Because all the connections are on one side (in anticipation of stacking these cells), I also made "front" and "rear" versions of endplates, inner/outer current collectors, and gaskets in the FreeCAD files. This will make low-volume prototyping a bit more expensive but more robust against leaks, which no one wants! [image: 1769763690358-037a7741-97dc-4012-8e95-cf8ab8760653-image.png] This is the dimension that went from 1 mm to 3 mm to facilitate using MP-6R pumps. [image: 1769763764115-d4ac6efb-4694-4d13-a941-8ffb85995001-image.png] We have the MP-6R now. It is the 6W high-flow version. the MP-10 is also 6W but lower flow / 50 % higher max pressure, then the MP-15R can do almost 3x higher pressure than the MP-6R but at 10 W. @danielfp248 can hopefully print the 3mm flow frames and I can get them at FOSDEM, then try them out. If it turns out we need the bigger pumps, I'll order them from AliExpress: [image: 1769763852108-f14b9379-cbc5-4542-940c-b33c0bacdb14-image.png]
  • Life Cycle Assessment (LCA) for the FBRC redox-flow battery

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    kirkK
    Hi all, and apologies for the delay! This year has started off with quite a lot of administrative burden for me and I haven't had as much time for research as I anticipated. @Santiago-Eduardo said in Life Cycle Assessment (LCA) for the FBRC redox-flow battery: Elektrolyte: The group noticed that two slightly different electrolyte compositions are mentioned. Sorry for the confusion, the correct mass composition can be found in the documentation here: https://fbrc.codeberg.page/rfb-dev-kit/electrolyte.html, the masses listed will prepare approximately 10 mL of electrolyte. @Santiago-Eduardo said in Life Cycle Assessment (LCA) for the FBRC redox-flow battery: They assume an 880 ml volume for one single cell. Do you estimate this volume to maintain the obtained results until now? Is this the volume foreseen to achieve the 22 Wh/single large-format cell? Yes this would be correct volume scaling for the large-format cell, although of course still a lot smaller than an eventual life-size system! It is basically t]e volume that we will end up using for our tests of the large-format cell (still to come). @Santiago-Eduardo said in Life Cycle Assessment (LCA) for the FBRC redox-flow battery: The group is assuming the EE value to estimate this. This value does not include energy demand from pumps and electronics, correct? Correct, these losses are often summed up in RFB literature as "balance-of-plant" or BoP if you want to search for some values. @Santiago-Eduardo said in Life Cycle Assessment (LCA) for the FBRC redox-flow battery: Meaning: to store 1 Wh, 1.56 Wh needs to be taken from the grid (excluding electronics and pumps). Does this make sense, or are we oversimplifying here? You've got it exactly! @Santiago-Eduardo said in Life Cycle Assessment (LCA) for the FBRC redox-flow battery: Used electricity For the same purpose of modelling the use phase, it is important to define from which country and what type of energy/electricity is being used to charge the electrolyte. Since the users of the FBRC battery can be anywhere, but are currently mostly centered in Europe, the group has decided to choose the European electricity grid mix data to represent the current FBRC reality. This makes sense to me. @Santiago-Eduardo said in Life Cycle Assessment (LCA) for the FBRC redox-flow battery: The separator, for instance, would be one of these peripheral impacts, since it would need to be replaced after some cycles (probably faster than the electrolyte). Since cycle durability of photo paper is still unknown, the group will model different scenarios from 10–100 cycles in steps of 30 cycles. Do you feel this is a reasonable range? Do you already now conditions such as density and flow rate the larger cell will work with? The group will assume 4 layers for the larger cell although in some parts are 3 layers stated. While separators can be replaced, I am doubtful in an industrial system that they would, due to the labor costs. From my understanding, Li-ion lifetimes are often given as 2,000 cycles to 80% of initial capacity; for flow batteries, the data isn't as solid, but for VRFB the lifetime claims are more on the scale of 20,000 cycles or 20 years, whichever comes sooner (taken with a grain of salt...). We haven't done any testing that long-term, so don't have much for your to extrapolate, but RFB technoeconomic papers with operation and maintenance (O&M) costs incorporated would give you a good idea of membrane/pump replacement frequency (if ever). I would increase the cycle range to much longer terms, with the upper end in the 1,000s at least. We aren't yet locked-in on flow rates for the large cell as we are still settling on choice of pumps and flow field design. @Santiago-Eduardo said in Life Cycle Assessment (LCA) for the FBRC redox-flow battery: The current BOM and building instructions do not provide specific links to purchase the necessary chemicals. To model the electrolyte production, including the transportation of each chemical, the group has assumed the following production locations based on market data and worldwide production trends. If your own experience differs in this, please do not hesitate to comment. These assumptions all make sense to me; Daramic separator (which we also use in addition to paper depending on the test) can/is produced in the EU though not exclusively. I hope this clears things up for you all somewhat, and again, sorry for the delay!
  • Following your documentation – feedback & questions

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    @danielfp248 I always performed more cycles before starting 40 mA / 100 mAh charging (10 half-cycles at 20 mA / 10 mAh + 4–10 half-cycles at 30 mA / 10 mAh). The cell was also wet with demineralized water (leakage test). Could this also be the cause? I was also always using the membrane frame. Wouldn't the electrolyte leak through the paper membrane? @kirk Apart from solving the electrolyte leakage issue, does this "pulling-through configuration" improve the total capacity of the system in any other way? Also, I am wondering whether you are using the default flow frame from the documentation (2 mm thick, right?) or a different one with another thickness and the 0.1 mm silicone gaskets.
  • MyStat control software refactor

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    Hi sepi, your refactor-modular works on my PCs: my mainPC (Kubuntut 2404) and two Notebooks for measurements (Kubuntu 2404 and Win11), thanks. I'm waiting for your calibration wizard. My hardware is waiting incl. Mystat, but till now I did not do tests.
  • My build (very slowly progressing)

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    kirkK
    @sepi Without the four-wire control the pump speeds are definitely harder to manage, sorry to hear that, though the PWM regulator may help. Can you visually see how different the rotation speeds are? That should be rough proxy for volumetric flowrate. I am not surprised they won't spin below 11 V. @sepi said in My build (very slowly progressing): Is this 20-40ml/min measured with the cell in line or just the pump. Ideally best to measure with the cell inline, to be closer to the actual conditions. However, as the tubing wears, this can drift, just FYI. Not a huge deal but something to be aware of. @sepi said in My build (very slowly progressing): Is the figure obtained with water or electrolyte? Water for now, just as a proxy, minimize exposure to electrolyte. This is kind of a 1, maybe 2 significant digit measurement, no more (the volumetric flowrate). @sepi said in My build (very slowly progressing): What would you recommend doing against the excess flow? @sepi said in My build (very slowly progressing): the left passing up to 40% more water at the same voltage. At the same voltage, is the left pump spinning at (nearly) the same rate as the right? if they are spinning at the same rotational speed and the left is passing 40% more water, it sounds like there is some flow restriction in the right pump's flow loop. If they have identical flow loops (in terms of pressure drop), and are set at the same voltage, I would guess that they should rotate at similar speeds, but this may not be the case for the brushed motors (e.g. variance in motor properties). What is important for testing, is that both pumps are above a minimum flowrate to ensure good mass transfer, and that the pressure imbalance between the two sides isn't too great as to cause transfer of electrolyte from one side to another through the separator. If the flowrates aren't perfectly matched but those two previous conditions are met, it's not a big issue, although it's just better for repeatability for them to be the same.
  • Tygon chemical for sale

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    sepiS
    The tubing is gone now, thanks for buying at my store
  • Thin sleeves to insulate screws (no more tape)

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    sepiS
    @doho that's a great idea, I'll give it a try!
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  • 3D printed barbed connector

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    sepiS
    My pumps didn't have them, only the ones built into the pump. I saw that on some of your pictures, you have additional fittings between the different elements, I guess to make it easier to connect and disconnect the cell. In the end, it might make more sense to just shrink the barbs on the flowframe and/or tank a bit so the tubing comes off mor easily.
  • Separator material

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    sepiS
    @danielfp248 ah, that makes sense as a last resort measure but would it not be nice to not lose charge? Well it all depends on how easiy it is to counteract by setting a different flow for the different electrolytes.
  • This topic is deleted!

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  • Theoretical Practical tank size limit

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    @Vorg We will slowly get there but no, right now we don't have any kWh capacity battery. As I mentioned, it will be several years before we get there. The fun is to walk this path and make everything open source on the way.
  • MyStat PCBs for free

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    @sepi Hi, if you do the selling of the tube, I would order 2 (two) meters.

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